Andrew Gewirth
Professor of Chemistry
Professor Andrew A. Gewirth received his A.B. from Princeton University in 1981 and his Ph.D. from Standford University in 1987. He joined the Illinois faculty in 1988 after postdoctoral work at the University of Texas, Austin. Research in his group focuses on the structure and reactivity of surfaces and interfaces.
Research
Research in our group focuses on the structure and reactivity of surfaces and interfaces. We utilize local probe microscopies in conjunction with electrochemical, computational, and spectroscopic methods. Electrochemical use of the Atomic Force Microscope (AFM) was developed in our laboratory.
Metal surfaces in electrochemical environments are important in satisfying future energy and remediation needs. One focus of recent activity is the four electron electroreduction of O2 to H2O. Despite intensive effort, little is understood about this reaction, which complicates design of new catalysts. We are using spectroscopic means on well-defined catalyst surfaces along with computational methods to interrogate intermediates and understand the mechanism of this reaction. The insight we obtain from these studies is used to design materials that may exhibit enhanced activity. We emphasize coupling inorganic materials, such as polyoxometalates, with electrochemical activity. These surfaces have potential use in fuel cells and other energy-related applications.
We examine electrode surfaces in order to elucidate properties of the electrochemical double layer and focus on fundamental properties of the electrified solid-liquid interface. For example, we use vibrational spectroscopic means to address, for the first time, the structure of water at this interface and the way in which the water molecules interact with the anions and cations that constitute the double layer. A related effort uses potential dependent "force spectroscopy" with the AFM to examine the composition of electrode materials.
Electrodeposition of Cu is the preferred method today to metallize semiconductors. Small organic and inorganic molecules control the texture of the electrodeposit, and developing an understanding of the way in which these molecules act becomes increasingly important as feature sizes decrease. We use vibrational spectroscopy and probe microscopy to interrogate these molecules and understand the way in which they moderate the electron transfer process occurring during deposition.
A new focus examines the behavior of supported phospholipid bilayers both by themselves and after introduction of relevant materials including polymers and proteins. We examine the interaction of different proteins with each other and with other constituents of the bilayer film as a function of external variables such as temperature, pressure, and applied field. These measurements are providing insight into the behavior of proteins and other constituents in cell membranes.
Publications
"Potential Dependent Organization of Water at the Electrified Metal-Liquid Interface" Schultz, Z. D.; Shaw, S. K.; Gewirth, A. A. J. Am. Chem. Soc. 2005, 127, 15916-15922.
"Mechanism of Oxygen Electroreduction on Au Surfaces in Basic Media" Kim, J.; Gewirth, A. A. J. Phys. Chem B 2006, 110, 2565-2571.
"Electrostatic Stitching in Gel-Phase Supported Phospholipid Bilayers" Zhang, L.; Spurlin, T.; Gewirth, A. A.; Granick, S. J. Phys. Chem. B 2006 110, 33-35.
"Poly-L-Lysine Induced Morphology Changes in Mixed Anionic/Zwitterionic and Neat Zwitterionic Supported Phospholipid Bilayers" Spurlin, T. A.; Gewirth, A. A. Biophys. J. 2006, 91, 2919-2927.
"In Situ EC-STM Studies of MPS, SPS, and Chloride on Cu(100); Structural Studies of Accelerators for Dual Damascene Electrodeposition" Bae, S.-E.; Gewirth, A. A. Langmuir, 2006 22, 10315-10321.
"Anion Effects on Cu-BTA Film Formation: Implications for CMP" Stewart, K. L.; Zhang, J.; Li, S.; Carter, P. W.; Gewirth, A. A. J. Electrochem. Soc. 2007, 154, D57-D63
Gewirth, Andrew A. Review of "Modern Aspects of Electrochemistry, No. 39." Edited by C. G. Vayenas, Ralph E. White, and Maria E. Gamboa-Adelco. J. Am. Chem. Soc. 2006, 128, 15548.
"C60 Decoration of Lipid Bilayers" Spurlin, T. A.; Gewirth, A. A. Nano Lett. 2007, 7, 531-535.
"Atomic Force Microscopic Study of Polymeric Film Growth in Copper Electroplating Bath With Benzotriazole" Feng, Z. V.; Gewirth, A. A. J. Electroanal. Chem. 2007 601, 242-50.
"Pb Electrodeposition on (111)-Textured Cu in The Presence and Absence of Cl-: A Combined Oblique Incidence Reflectivity Difference and In-Situ AFM Study" Wu, G.-Y.; Bae, S.-E.; Gewirth, A. A.; Gray, J.; Zhu, X. D.; Moffat, T. P.; Schwarzacher, W. Surf. Sci. 2007 601, 1886-1891.
"Nitrate Adsorption and Reduction on Cu(100) in Acidic Solution" Bae, S.-E.; Stewart, K. L.; Gewirth, A. A. J. Am. Chem. Soc. 2007 129, 10171-10180.
"Electrocatalysis of Oxygen Reduction by Cu-containing Polymer Films on Glassy Carbon Electrodes" Kim, J.; Gewirth, A. A. Bull. Kor. Chem. Soc. 2007, 28, 1322-28.
"Potential Dependence of the Structure of Water at the Hydrophobic-Liquid Interface" Shaw, S. K.; Gewirth, A. A. J. Electroanal. Chem. 2007, in press.
"Mechanism of Electrochemical Reduction of Hydrogen Peroxide on Copper in Acidic Sulfate Solutions" Stewart, K. L.; Gewirth, A. A. Langmuir. 2007, 23, 9911-9918
"SERS Examination of Saccharin Adsorption on Ni Electrodes" Kwon, H.-C.; Gewirth, A. A.; J. Electrochem. Soc. 2007, 154, D577-D583.
"Charge Dependence of a Nano-scale Supercrystal Phase in a Supported Lipid Bilayer" Spurlin, T. A.; Gewirth, A. A. J. Am. Chem. Soc. 2007 129, 11906-11907
